A Sustainable and Efficient Synthesis of Benzyl Phosphonates Using PEG/KI Catalytic System

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F16%3A33161187" target="_blank" >RIV/61989592:15310/16:33161187 - isvavai.cz</a>
Result on the web
<a href="http://journal.frontiersin.org/article/10.3389/fchem.2016.00035/full" target="_blank" >http://journal.frontiersin.org/article/10.3389/fchem.2016.00035/full</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3389/fchem.2016.00035" target="_blank" >10.3389/fchem.2016.00035</a>

Result language
angličtina
Original language name
A Sustainable and Efficient Synthesis of Benzyl Phosphonates Using PEG/KI Catalytic System
Original language description
An efficient and expedient protocol for the synthesis of benzyl phosphonates using KI/K2CO3 as a catalytic system and PEG-400 as benign solvent has been developed. The reaction proceeds smoothly at room temperature achieving excellent selectivity and yield of the corresponding products. The combination of PEG-400, KI, and K2CO3 in this reaction avoids the need of volatile/toxic organic solvents and reactive alkali metals or metal nanoparticles/hydrides. We believe that this benign combination (PEG-400 and KI) could be used for other related organic transformations.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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