Environmentally Benign Bioderived Carbon Microspheres-Supported Molybdena Nanoparticles as Catalyst for the Epoxidation Reaction
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F17%3A73582706" target="_blank" >RIV/61989592:15310/17:73582706 - isvavai.cz</a>
Result on the web
<a href="http://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.6b02229" target="_blank" >http://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.6b02229</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acssuschemeng.6b02229" target="_blank" >10.1021/acssuschemeng.6b02229</a>
Alternative languages
Result language
angličtina
Original language name
Environmentally Benign Bioderived Carbon Microspheres-Supported Molybdena Nanoparticles as Catalyst for the Epoxidation Reaction
Original language description
A one pot synthesis of molybdenum oxide nanoparticles (NPs supported on bioderived carbon microspheres is reported. The catalyst was synthesized by the low temperature hydrothermal (LTH) method using D-glucose and bagasse as the carbon source. The carbonization of bagasse resulted in the formation of nonuniform carbon microspheres while glucose resulted in uniform carbon spheres. SEM and STEM elemental mapping show the uniform distribution of molybdenum oxide NPs over the carbon microspheres. XPS spectroscopy confirmed that molybdenum was in the Mo6+ oxidation state. The 1% MoO3 supported on carbon microspheres derived from D-glucose showed excellent catalytic activity up to 100% olefin conversion with 100% epoxide selectivity using organic tent-butyl hydroperoxide as an oxidant. The catalyst was successfully used for up to five cycles without losing substantial activity and selectivity.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
21001 - Nano-materials (production and properties)
Result continuities
Project
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Continuities
N - Vyzkumna aktivita podporovana z neverejnych zdroju
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Sustainable Chemistry & Engineering
ISSN
2168-0485
e-ISSN
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Volume of the periodical
5
Issue of the periodical within the volume
1
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
904-910
UT code for WoS article
000391246000102
EID of the result in the Scopus database
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