Selective photocatalysis of lignin-inspired chemicals by integrating hybrid nanocatalysis in microfluidic reactors

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F17%3A73583688" target="_blank" >RIV/61989592:15310/17:73583688 - isvavai.cz</a>

Result on the web

<a href="http://pubs.rsc.org/en/content/articlepdf/2017/cs/c7cs00257b" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2017/cs/c7cs00257b</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c7cs00257b" target="_blank" >10.1039/c7cs00257b</a>

Result language

angličtina

Original language name

Selective photocatalysis of lignin-inspired chemicals by integrating hybrid nanocatalysis in microfluidic reactors

Original language description

This tutorial review assesses the available and possible strategies for attaining higher selectivity and yield of value-added chemicals from lignin using nanocatalysts embedded in a photomicroreactor. The design of the photomicroreactor, the choice of photocatalysts and the techniques for assembling the catalysts in such confined spaces are crucial elements. Lignin, a predominant industrial byproduct and pollutant, has been recognized today as a rich reservoir for aromatic chemicals and a prominent resource. The conventional batch photocatalytic studies on lignin, often using dissolved lignin under alkaline conditions, often generates a wide range of valuable organic chemicals which find applications in the pharmaceutical, food processing, cosmetic and fine chemical industries. The role of photocatalysis in such lignin depolymerizations is questionable as the dissolution procedure initiates fragmentation of lignin prior to light exposure. The complexity of the lignin structure also impedes necessary and decisive information to understand the reaction mechanism during such reactions in batch photoreactors. Considering these facts, photocatalysis studies on lignin entail a thoughtful reevaluation and focus on understanding the role of photocatalysis in the product generation and authenticating the implicated reaction mechanisms. The development of a photocatalytic system for lignin depolymerization in a continuous microreactor is a superior approach for the generation of valuable products emanating from lignin depolymerization and the successful execution of such strategies can pave the way for the commercialization of bio-based chemicals.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10401 - Organic chemistry

Project

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Continuities

N - Vyzkumna aktivita podporovana z neverejnych zdroju

Publication year

2017

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Chemical Society Reviews

ISSN

0306-0012

e-ISSN

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Volume of the periodical

46

Issue of the periodical within the volume

22

Country of publishing house

GB - UNITED KINGDOM

Number of pages

12

Pages from-to

6675-6686

UT code for WoS article

000415103200001

EID of the result in the Scopus database

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