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Electrokinetic preconcentration of magnetite core - carboxylic shell nanoparticles by capillary electrophoresis

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F17%3A73583925" target="_blank" >RIV/61989592:15310/17:73583925 - isvavai.cz</a>

  • Result on the web

    <a href="http://www.sciencedirect.com/science/article/pii/S0021967317304892" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0021967317304892</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.chroma.2017.03.079" target="_blank" >10.1016/j.chroma.2017.03.079</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electrokinetic preconcentration of magnetite core - carboxylic shell nanoparticles by capillary electrophoresis

  • Original language description

    Online electrokinetic preconcentration of magnetite core/carboxylic shell nanoparticles (MNPs) was studied by capillary electrophoresis using reversed and suppressed electroosmotic flow (EOF). 50 mM sodium borate pH 9.5 was used as a background electrolyte. CTAB additive was used to reverse EOF and commercial polyvinylalcohol (PVA)-coated capillaries were used for EOF suppressed studies. Analyses in PVA-coated capillaries were more reproducible and therefore, the setup was further optimized in terms of water plug injection time, sample injection time, and voltage. Within the optimal conditions, the MNPs dispersed in water are electrokinetically loaded into BGE consisting of 50 mM sodium borate pH 9.5 using -10 kV for 120 s. In comparison with the hydrodynamic injection of 5 s by 50 mbar, the electrokinetic injection allows 860-fold preconcentration of MNPs

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10406 - Analytical chemistry

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Chromatography A: Symposium Volumes

  • ISSN

    0021-9673

  • e-ISSN

  • Volume of the periodical

    1499

  • Issue of the periodical within the volume

    MAY

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    5

  • Pages from-to

    217-221

  • UT code for WoS article

    000401394200024

  • EID of the result in the Scopus database