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Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F18%3A73591059" target="_blank" >RIV/61989592:15310/18:73591059 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0277538718304844" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0277538718304844</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.poly.2018.08.019" target="_blank" >10.1016/j.poly.2018.08.019</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence

  • Original language description

    The present article reports on the syntheses, crystal structures and luminescence properties of three solvate forms of a zinc(II) complex containing 4-{(E)-[(2-fluorophenyl)imino]methyl)-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one (HL). The reaction of zinc(II)acetate with the HL ligand in ethanol and acetonitrile led to the formation of two solvate analogues [Zn(L)(2)]center dot Solv (Solv - ethanol (1) and acetonitrile (2)). The properties of the [Zn(L)(2)]center dot Solv complexes were investigated by UV-Vis absorption and fluorescence emission spectroscopy, and the density functional theory calculations. Bader&apos;s topological analysis was performed to investigate the electronic peculiarities of Zn(II) polyhedra and non-covalent interactions within crystal packing of studied solvates. (C) 2018 Elsevier Ltd. All rights reserved.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

    <a href="/en/project/LO1305" target="_blank" >LO1305: Development of the center of advanced technologies and materials</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    POLYHEDRON

  • ISSN

    0277-5387

  • e-ISSN

  • Volume of the periodical

    155

  • Issue of the periodical within the volume

    NOV

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    202-208

  • UT code for WoS article

    000449137000025

  • EID of the result in the Scopus database

    2-s2.0-85052641720