Carboxymethylcellulose-based magnetic Au or Ag nanosystems: Eminent candidates in catalysis, sensing applications based on SERS, and electrochemistry

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F19%3A73594905" target="_blank" >RIV/61989592:15310/19:73594905 - isvavai.cz</a>

Result on the web

<a href="https://www.sciencedirect.com/science/article/pii/S2352940718306127" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2352940718306127</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.apmt.2018.12.001" target="_blank" >10.1016/j.apmt.2018.12.001</a>

Result language

angličtina

Original language name

Carboxymethylcellulose-based magnetic Au or Ag nanosystems: Eminent candidates in catalysis, sensing applications based on SERS, and electrochemistry

Original language description

An increasing demand for metal gold-and/or silver-based nanomaterials in optics, catalysis, and electrochemical sensing research calls for the development of a new, clean, and environmentally friendly methodology for the production of metal-containing composites. Herein, we report a novel method for fabrication of dispersed carboxymethylcellulose stabilized iron oxide nanoparticles capable to adsorb silver and gold ions onto the surface. Simultaneously, Ag or Au ions are trapped on the magnetic carrier surface and reduced into metal nanoparticles without the action of another reducing agent. The magnetic silver nanocomposite with dumbbell-like structures and magnetic gold nanocomposite with strawberry-like structures, both of different composition (5, 10, and 20 wt.% metal contents), were prepared and characterized by high-resolution transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray powder diffraction, and atomic absorption spectroscopy. Subsequently, the prepared magnetic silver and gold nanocomposites (cMNPs-Ag and cMNPs-Au, respectively) were studied as sufficient candidates in catalysis, sensing applications based on SERS, and electrochemistry. The catalytic properties were demonstrated with the reduction of 4-nitrophenol to 4-aminophenol as a model reaction, where very high rate constants of nanocomposites ranging between 0.25 and 4.12 min(-1) were determined. The TOF values were calculated to be from 20.87 to 95.34 min(-1). Glassy carbon electrodes modified with cMNPs-Au or cMNPs-Ag nanocomposites were used for successful determination of H2O2 by means of cyclic voltammetry. Obtained results revealed the well-defined reduction peak around -0.45 V indicating small overpotential necessary for H2O2 detection and detection limits were found to be 2.82 x 10(-7) mol L-1 (cMNPs-Au) and 3.04 x 10(-7) mol L-1 (cMNPs-Ag). Utilization of nanocomposites as active SERS substrates was demonstrated on the analysis of Rhodamine 6G. The determined enhancement factors were 2 x 10(7) (cMNPs-Au, 20 wt.% Au content) and 3.2 x 10(7) (cMNP-Ag, 20 wt.% Ag content).

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10403 - Physical chemistry

Project

<a href="/en/project/LO1305" target="_blank" >LO1305: Development of the center of advanced technologies and materials</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2019

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Applied Materials Today

ISSN

2352-9407

e-ISSN

—

Volume of the periodical

14

Issue of the periodical within the volume

MAR

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

8

Pages from-to

143-150

UT code for WoS article

000458430900016

EID of the result in the Scopus database

2-s2.0-85058237355