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A Novel Strategy for Selective O-Methylation of Glycerol in Subcritical Methanol

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F19%3A73595351" target="_blank" >RIV/61989592:15310/19:73595351 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6536655/" target="_blank" >https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6536655/</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3389/fchem.2019.00357" target="_blank" >10.3389/fchem.2019.00357</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    A Novel Strategy for Selective O-Methylation of Glycerol in Subcritical Methanol

  • Original language description

    A new regioselective approach has been elaborated for the selective conversion of bio-based glycerol into the monomethyl derivative using sub/supercritical methanol. The reaction was realized in a batch process using three reactive components, namely, glycerol, methanol, and potassium carbonate to selectively produce the 3-methoxypropan-1,2-diol in mild yields; the mechanism of the O-methylation has been delineated using labeled methanol and GC-MS experiments.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

  • Continuities

    N - Vyzkumna aktivita podporovana z neverejnych zdroju

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Frontiers in Chemistry

  • ISSN

    2296-2646

  • e-ISSN

  • Volume of the periodical

    7

  • Issue of the periodical within the volume

    MAY

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    7

  • Pages from-to

    "357-1"-"357-7"

  • UT code for WoS article

    000468400700001

  • EID of the result in the Scopus database

    2-s2.0-85068498570