Recent advances in N-formylation of amines and nitroarenes using efficient (nano)catalysts in eco-friendly media

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F19%3A73595444" target="_blank" >RIV/61989592:15310/19:73595444 - isvavai.cz</a>

Result on the web

<a href="https://link.springer.com/article/10.1007/s10098-019-01702-3" target="_blank" >https://link.springer.com/article/10.1007/s10098-019-01702-3</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c9gc01822k" target="_blank" >10.1039/c9gc01822k</a>

Result language

angličtina

Original language name

Recent advances in N-formylation of amines and nitroarenes using efficient (nano)catalysts in eco-friendly media

Original language description

N-Formylation of amines or nitroarenes using catalysts is a prominent, chemoselective and efficient reaction for the fabrication of formyl amides. Formamides are one of the most valuable intermediates in pharmacological syntheses or important building blocks in synthetic and industrial organic chemistry, and have found widespread usage as pharmaceutically valuable intermediates and promising reagents in organic transformations. Formylation reactions catalyzed by unsupported or material-supported nanostructure catalysts are gaining significance; the conversion of all types of amines to formamides has been accomplished using reagents and an assortment of nanocatalysts, transition metal catalysts, organic catalysts and acidic catalysts. Amongst these, the most useful catalysts are often metal/metal oxide-based catalysts which are versatile and efficient. Heterogeneous nanocatalysts have found a unique niche for various N-formylation reactions owing to their thermal stability, reusability, large specific surface area, and high catalytic performance; nanotechnological innovations have enabled the emergence of techniques for fabricating these specific (nano)catalysts. In this overview, recent developments in the preparation, characterization, and catalytic application of various catalysts towards the N-formylation of amines or nitroarenes are presented and these are conducted in eco-friendly and green media including water, polyethylene glycol, and ionic liquids, as well as under solvent-free conditions.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10403 - Physical chemistry

Project

—

Continuities

N - Vyzkumna aktivita podporovana z neverejnych zdroju

Publication year

2019

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

GREEN CHEMISTRY

ISSN

1463-9262

e-ISSN

—

Volume of the periodical

21

Issue of the periodical within the volume

19

Country of publishing house

GB - UNITED KINGDOM

Number of pages

24

Pages from-to

5144-5167

UT code for WoS article

000488459900001

EID of the result in the Scopus database

2-s2.0-85072911424