Synthesis of [15N4]purine labelled cytokinin glycosides derived from zeatins and topolins with 9-β-D, 7-β-D-glucopyranosyl, or 9-β-D-ribofuranosyl group

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F19%3A73596946" target="_blank" >RIV/61989592:15310/19:73596946 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/jlcr.3702" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/jlcr.3702</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/jlcr.3702" target="_blank" >10.1002/jlcr.3702</a>

Result language
angličtina
Original language name
Synthesis of [15N4]purine labelled cytokinin glycosides derived from zeatins and topolins with 9-β-D, 7-β-D-glucopyranosyl, or 9-β-D-ribofuranosyl group
Original language description
Synthesis of [15N4]purine labelled cytokinine glycosides derived from zeatins and topolins containing a 9-β-D, 7-β-D-glucopyranosyl, or 9-β-D-ribofuranosyl group is described. These N6-substituted adenine derivatives are intended as internal analytic standards for phytohormone analysis. All labelled compounds were prepared from 6-chloro[15N4]purine (1). The equilibrium reaction of 1 with acetobromo--D-glucose gave isomeric 7-β-D (3) and 9-β-D (4) chloro glucosyl precursors, which were treated with the corresponding amines to get desired labelled cytokinin 7-β-D (6) and 9-β-D (5) glucopyranosides. Cytokinins containing 9-β-D-ribofuranosyl group (8) were obtained by direct enzymatic transglycosylation reaction of cytokinins (7) prepared from 6-chloro[15N4]purine (1).
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/TE02000058" target="_blank" >TE02000058: Center of competence for molecular diagnostics and personalized medicine</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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