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Supported heterogeneous nanocatalysts in sustainable, selective and eco-friendly epoxidation of olefins

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F20%3A73601918" target="_blank" >RIV/61989592:15310/20:73601918 - isvavai.cz</a>

  • Result on the web

    <a href="https://pubs.rsc.org/en/content/articlehtml/2020/gc/d0gc01927e" target="_blank" >https://pubs.rsc.org/en/content/articlehtml/2020/gc/d0gc01927e</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d0gc01927e" target="_blank" >10.1039/d0gc01927e</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Supported heterogeneous nanocatalysts in sustainable, selective and eco-friendly epoxidation of olefins

  • Original language description

    Epoxides are highly useful intermediates in the production of many chemicals, pharmaceuticals, perfumes, and polymers. In view of the continuing demand for epoxides, it is imperative to develop greener and sustainable reaction protocols. To address these challenges, highly active, selective and efficient heterogeneous catalysts have been designed. Historically, there has been a progressive replacement of hazardous peracids and chlorohydrin-based epoxidation of olefins by metal catalysts deployingtert-butyl hydroperoxide (TBHP), hydrogen peroxide (H2O2) and molecular oxygen (O-2) as oxidants. The main focus of this review is to epitomize the wide scope of supported metal nanocatalysts that have been applied for the epoxidation of olefins. The synthesis, activity and selectivity of the nanocatalytic materials along with a critical appraisal of the performance of the support in the epoxidation of olefins are accentuated.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    21001 - Nano-materials (production and properties)

Result continuities

  • Project

  • Continuities

    N - Vyzkumna aktivita podporovana z neverejnych zdroju

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    GREEN CHEMISTRY

  • ISSN

    1463-9262

  • e-ISSN

  • Volume of the periodical

    22

  • Issue of the periodical within the volume

    18

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    35

  • Pages from-to

    5902-5936

  • UT code for WoS article

    000571356300002

  • EID of the result in the Scopus database

    2-s2.0-85092312324