Pd modified prussian blue frameworks: Multiple electron transfer pathways for improving catalytic activity toward hydrogenation of nitroaromatics
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F20%3A73601967" target="_blank" >RIV/61989592:15310/20:73601967 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S2468823120302261" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2468823120302261</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.mcat.2020.110967" target="_blank" >10.1016/j.mcat.2020.110967</a>
Alternative languages
Result language
angličtina
Original language name
Pd modified prussian blue frameworks: Multiple electron transfer pathways for improving catalytic activity toward hydrogenation of nitroaromatics
Original language description
Prussian blue analogs (PBAs) exhibit potential as low-cost and eco-friendly nanocatalysts that can be fabricated with ease. However, the PBA framework structure suffers from poor electronic conductivity, which limits the catalytic efficiency for this class of materials. Noble metals represent an alternative class of materials that display inherent catalytic activity but suffer from aggregation, ultimately reducing the amount of accessible catalytic sites. Herein, we demonstrate a combinatory approach that circumvents the known disadvantages with these classes of catalytic materials in which PBA-supported nanocatalysts were synthesized. These composite materials exhibit excellent catalytic activity for the reduction of nitroaromatics to aminoaromatics while displaying longterm cycling stability, which is attributed to the availability of multiple electron transfer pathways. Overall, this work opens the study on the assembly of PBA-supported heterogeneous nanocatalysts and potentially paves the way toward future applications.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
N - Vyzkumna aktivita podporovana z neverejnych zdroju
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Molecular Catalysis
ISSN
2468-8231
e-ISSN
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Volume of the periodical
492
Issue of the periodical within the volume
AUG
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
9
Pages from-to
"110967-1"-"110967-9"
UT code for WoS article
000549100200009
EID of the result in the Scopus database
2-s2.0-85085374212