Boosting Aerobic Oxidation of Alcohols via Synergistic Effect between TEMPO and a Composite Fe3O4/Cu-BDC/GO Nanocatalyst
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F20%3A73602371" target="_blank" >RIV/61989592:15310/20:73602371 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/pdf/10.1021/acsomega.9b04209" target="_blank" >https://pubs.acs.org/doi/pdf/10.1021/acsomega.9b04209</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsomega.9b04209" target="_blank" >10.1021/acsomega.9b04209</a>
Alternative languages
Result language
angličtina
Original language name
Boosting Aerobic Oxidation of Alcohols via Synergistic Effect between TEMPO and a Composite Fe3O4/Cu-BDC/GO Nanocatalyst
Original language description
Fabrication of a nanocomposite catalyst via a novel and efficient strategy remains a challenge; Fe3O4 nanoparticles anchored on graphene oxide (GO) sheet-supported metal-organic frameworks (MOFs). In this study, the physicochemical properties of the ensuing Fe3O4/Cu-BDC/GO are investigated using Fourier transform infrared spectrum, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, energy-dispersive X-ray detector, and atomic absorption spectroscopy. The salient features of the nanocomposite such as Cu-MOF, synergistic effect with GO sheets, and magnetic separation characteristics make it an excellent ternary heterostructure for aerobic oxidation of alcohols. The proposed nanocatalyst and co-catalyst 2,2,6,6-tetramethylpiperidine-N-oxyl substantially enhance the catalytic performance for the aerobic oxidation under very mild and sustainable reaction conditions. The heterogeneity of Fe3O4/Cu-BDC/GO composite catalyst is affirmed with the added advantage that the initial activity is well maintained even after seven cycles.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
N - Vyzkumna aktivita podporovana z neverejnych zdroju
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Omega
ISSN
2470-1343
e-ISSN
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Volume of the periodical
5
Issue of the periodical within the volume
10
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
5182-5191
UT code for WoS article
000520853400052
EID of the result in the Scopus database
2-s2.0-85081702672