The Existence of a N -> C Dative Bond in the C-60-Piperidine Complex
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F20%3A73603955" target="_blank" >RIV/61989592:15310/20:73603955 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/21:00540182 RIV/61989592:15310/21:73610908 RIV/61989592:15640/21:73610908
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/ange.202012851" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/ange.202012851</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202012851" target="_blank" >10.1002/anie.202012851</a>
Alternative languages
Result language
angličtina
Original language name
The Existence of a N -> C Dative Bond in the C-60-Piperidine Complex
Original language description
The complexes formed between carbon allotropes (C-20, C-60 fullerenes, graphene, and single-wall carbon nanotubes) and piperidine have been investigated by means of computational quantum chemical and experimental IR and NMR techniques. Alongside hydrogen bonds, the C...N tetrel bond, and lone-pair...pi interactions, the unexpected N -> C dative/covalent bond has been detected solely in complexes of fullerenes with piperidine. Non-planarity and five-member rings of carbon allotropes represent the key structural prerequisites for the unique formation of a dative N -> C bond. The results of thermodynamics calculations, molecular dynamics simulations, and NMR and FTIR spectroscopy explain the specific interactions between C-60 and piperidine. The differences in behavior of individual carbon allotropes in terms of dative bonding formation brings a new insight into their controllable organic functionalization.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN
1433-7851
e-ISSN
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Volume of the periodical
133
Issue of the periodical within the volume
4
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
1970-1978
UT code for WoS article
000591753500001
EID of the result in the Scopus database
2-s2.0-85096719878