Cis and Trans Isomers of Fe(II) and Co(II) Complexes with Oxadiazole Derivatives - Structural and Magnetic Properties
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F21%3A73609422" target="_blank" >RIV/61989592:15310/21:73609422 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/21:10438710
Result on the web
<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202001148" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202001148</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.202001148" target="_blank" >10.1002/ejic.202001148</a>
Alternative languages
Result language
angličtina
Original language name
Cis and Trans Isomers of Fe(II) and Co(II) Complexes with Oxadiazole Derivatives - Structural and Magnetic Properties
Original language description
Four complexes with bidentate N,N-donors 2-(furan-2-yl)-5-(pyridin-2-yl)-1,3,4-oxadiazole (fpo) and 2-(pyridin-2-yl)-5-(thiophen-2-yl)-1,3,4-oxadiazole (pto) with general formula [M(L)(2)(NCS)(2)] (M=Co(II), L=fpo for (1); M=Co(II), L=pto for (2); M=Fe(II), L=fpo (3); M=Fe(II), L=pto (4)) are reported. Analysis and characterization of the samples was performed using standard physico-chemical techniques - elemental analysis, nuclear magnetic resonance, Fourier transform infrared spectroscopy, single-crystal X-ray diffraction. Magnetic properties for 1-4 revealed large magnetic anisotropy of Co(II) complexes, and AC susceptibility measurements confirmed their single-molecule magnetic behaviour. Furthermore, the theoretical calculations at DFT and CASSCF/NEVPT2 level of theory were exploited to better understand magnetism of these compounds.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN
1434-1948
e-ISSN
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Volume of the periodical
2021
Issue of the periodical within the volume
12
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
1190-1199
UT code for WoS article
000623884300001
EID of the result in the Scopus database
2-s2.0-85101866697