All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Hydroxido supported and differently networked octanuclear Ni(6)Ln(2) [Ln = Gd-III and Dy-III] complexes: structural variation, magnetic properties and theoretical insights

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F21%3A73609425" target="_blank" >RIV/61989592:15310/21:73609425 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216305:26620/21:PU140704

  • Result on the web

    <a href="https://pubs.rsc.org/en/content/articlehtml/2021/dt/d0dt04168h" target="_blank" >https://pubs.rsc.org/en/content/articlehtml/2021/dt/d0dt04168h</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d0dt04168h" target="_blank" >10.1039/d0dt04168h</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Hydroxido supported and differently networked octanuclear Ni(6)Ln(2) [Ln = Gd-III and Dy-III] complexes: structural variation, magnetic properties and theoretical insights

  • Original language description

    The design and synthesis of a Schiff base H2L, (2-{[(2-hydroxy-3-methoxybenzyl)imino]methyl)phenol), bearing an ONOO donor set has been explored for its reactivity pattern with LnCl(3)center dot 6H(2)O (Ln = Gd-III and Dy-III) and Ni(CH3CO2)(2)center dot 4H(2)O in the presence of NEt3 for molecular aggregation. Coordination driven spontaneous self-assembly reactions provide (Gd2Ni6L4(mu(3)-OH)(6)(mu-OH)(2)(CH3CO2)(2)(mu-H2O)(2)(H2O)(3)(MeOH)]center dot 8H(2)O (1) having a &apos;butterfly-shaped&apos; core and [Dy2Ni6L4(mu(3)-OH)(4)(mu-Cl)(2)Cl-4(H2O)(2)(MeOH)(2)]center dot 2MeOH center dot 4H(2)O (2) with a &apos;candy-shaped&apos; core. Fusion of six partial cubane units led to a mineral-like core in 1, developed around the central Ni-2(OH)(2) moiety, whereas in the case of 2, four such partial cubanes collapsed on Dy-2(OH)(2). Direct-current (dc) magnetic susceptibility measurements revealed that predominant ferromagnetic interactions lead to a high-spin S = 13 ground state for 1. Complex 2 exhibits slow relaxation of magnetization under an applied small dc field with an energy barrier to reorientation of the magnetization, U-eff = 19.3 K. The static and dynamic magnetic data are analysed and corroborated by density functional theory (DFT) and detailed CASSCF based calculations.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Dalton Transactions

  • ISSN

    1477-9226

  • e-ISSN

  • Volume of the periodical

    50

  • Issue of the periodical within the volume

    14

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    13

  • Pages from-to

    5023-5035

  • UT code for WoS article

    000633045300001

  • EID of the result in the Scopus database

    2-s2.0-85104266374