Synthesis, characterization, magnetism and theoretical analysis of hetero-metallic [Ni(2)Ln(2)] partial di-cubane assemblies
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F21%3A73609446" target="_blank" >RIV/61989592:15310/21:73609446 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2021/DT/D1DT00510C" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/DT/D1DT00510C</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1dt00510c" target="_blank" >10.1039/d1dt00510c</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis, characterization, magnetism and theoretical analysis of hetero-metallic [Ni(2)Ln(2)] partial di-cubane assemblies
Original language description
A family of four isostructural [Ln(2)Ni(2)(L)(2)(mu(3)-OCH3)(2)(mu(1,3)-PhCO2)(2)(PhCO2)(2)(CH3OH)(4)]center dot 2CH(3)OH (where Ln = Gd (1), Tb (2), Dy (3) and Ho (4)1 complexes has been synthesized using Schiff base ligand 2-[{(2-hydroxybenzyl)imino)methyl]-6-methoxyphenol (H2L). All the complexes possess a partial di-cubane core structure where the growth of the core is contingent upon the ligand anions and solvent generated mu(3)-OCH3 groups. DC magnetic analysis revealed dominating ferromagnetic interactions between the metal ions, however, we find no slow relaxation characteristics in the AC susceptibility. Further insight into the magnetic behavior of the reported complexes was achieved using DFT and CASSCF theoretical calculations, leading to the comprehension of the fast relaxation characteristics observed by magnetometry.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Dalton Transactions
ISSN
1477-9226
e-ISSN
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Volume of the periodical
50
Issue of the periodical within the volume
36
Country of publishing house
GB - UNITED KINGDOM
Number of pages
11
Pages from-to
12517-12527
UT code for WoS article
000683436500001
EID of the result in the Scopus database
2-s2.0-85115624568