Anion-Dependent Synthesis of Cu(II) Complexes with 2-(1H-Tetrazol-5-yl)-1H-indole: Synthesis, X-Ray Structures, and Radical Scavenging Activity
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F21%3A73609562" target="_blank" >RIV/61989592:15310/21:73609562 - isvavai.cz</a>
Result on the web
<a href="https://www.hindawi.com/journals/bca/2021/6736908/" target="_blank" >https://www.hindawi.com/journals/bca/2021/6736908/</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1155/2021/6736908" target="_blank" >10.1155/2021/6736908</a>
Alternative languages
Result language
angličtina
Original language name
Anion-Dependent Synthesis of Cu(II) Complexes with 2-(1H-Tetrazol-5-yl)-1H-indole: Synthesis, X-Ray Structures, and Radical Scavenging Activity
Original language description
Two mononuclear Cu(II) complexes, [Cu(phen)2(HL)]ClO4·H2O·2DMF (1) and [Cu(phen)2(HL)2]·EtOH (2), comprising 1,10- phentantroline (phen) and 2-(1H-tetrazol-5-yl)-1H-indole ligand (H2L) ligands are reported. Analysis and characterization of the samples were performed using standard physicochemical techniques, elemental analysis, nuclear magnetic resonance, Fourier transform infrared spectroscopy, and UV-vis spectroscopy. Single-crystal X-ray crystallography revealed the formation of a pentacoordinate complex in 1 and a hexacoordinate complex in 2, in which the anionic ligand HL− has undergone monodentate coordination through the tetrazole unit. Furthermore, the crystal structure of H2L·MeOH is also discussed. (e potential application of compounds 1 and 2 in bioinorganic chemistry was addressed by investigating their radical scavenging activity with the 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) and the results were supported also by theoretical calculations.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
BIOINORGANIC CHEMISTRY AND APPLICATIONS
ISSN
1565-3633
e-ISSN
—
Volume of the periodical
2021
Issue of the periodical within the volume
DEC
Country of publishing house
IL - THE STATE OF ISRAEL
Number of pages
12
Pages from-to
"6736908-1"-"6736908-12"
UT code for WoS article
000738917400001
EID of the result in the Scopus database
2-s2.0-85122756407