ON/OFF Photo(switching) along with Reversible Spin-State Change and Single-Crystal-to-Single-Crystal Transformation in a Mixed-Valence Fe(II)Fe(III) Molecular System
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F22%3A73619229" target="_blank" >RIV/61989592:15310/22:73619229 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c03972" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c03972</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.2c03972" target="_blank" >10.1021/acs.inorgchem.2c03972</a>
Alternative languages
Result language
angličtina
Original language name
ON/OFF Photo(switching) along with Reversible Spin-State Change and Single-Crystal-to-Single-Crystal Transformation in a Mixed-Valence Fe(II)Fe(III) Molecular System
Original language description
A mixed-valence Fe(II)Fe(III) molecular system, {[Fe(pzTp)(CN)3]2[Fe(bik)2]2}·[Fe(pzTp)(CN)3]2·4MeOH (1·4MeOH) (bik = bis-(1-methylimidazolyl)-2-methanone, pzTp = tetrakis(pyrazolyl)borate), exhibits single-crystal-to-single-crystal (SC-SC) transformation while increasing the temperature and is converted into {[Fe(pzTp)(CN)3]2[Fe(bik)2]2}·[Fe(pzTp)(CN)3]2 (1). Both complexes exhibit thermo-induced spin-state switching behavior along with reversible SC-SC transformation, where the low-temperature [FeIIILSFeIILS]2 phase transforms into a high-temperature [FeIIILSFeIIHS]2 phase. 1·4MeOH exhibits an abrupt spin-state switching with T1/2 at 355 K, whereas 1 undergoes a gradual and reversible spin-state switching with a lower T1/2 at 338 K. Astonishingly, 1 exhibits ON/OFF photo-induced spin-state switching with TLIESST = 67 K, whereas 1·4MeOH does not show such an effect.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
21001 - Nano-materials (production and properties)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
INORGANIC CHEMISTRY
ISSN
0020-1669
e-ISSN
1520-510X
Volume of the periodical
62
Issue of the periodical within the volume
23
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
8794-8802
UT code for WoS article
000989035900001
EID of the result in the Scopus database
2-s2.0-85149369938