Synthesis and Chiroptical Properties of a Chiral Isotopologue of syn-Cryptophane-B

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F23%3A73619058" target="_blank" >RIV/61989592:15310/23:73619058 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.joc.2c03101" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.joc.2c03101</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.joc.2c03101" target="_blank" >10.1021/acs.joc.2c03101</a>

Result language
angličtina
Original language name
Synthesis and Chiroptical Properties of a Chiral Isotopologue of syn-Cryptophane-B
Original language description
We report the synthesis and absolute configuration (AC) of a chiral isotopologue of syn-cryptophane-B. Low chiral signatures were measured by polarimetry and electronic circular dichroism, whereas most significant chiroptical effects were observed by vibrational circular dichroism (VCD) and Raman optical activity (ROA). The comparison of experimental VCD and ROA spectra with those predicted by DFT calculations allows the determination of the AC of the two enantiomers as (−)589-MP-syn-2 and (+)589-PM-syn-2.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
<a href="/en/project/GA22-04669S" target="_blank" >GA22-04669S: Sensitivity Enhancement of Vibrational Optical Activity Spectroscopy for Biomolecules</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)