Asymmetric Supercapacitors: Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitors

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F21%3A73610984" target="_blank" >RIV/61989592:15640/21:73610984 - isvavai.cz</a>

Alternative codes found

RIV/61989592:15310/21:73610984

Result on the web

<a href="https://onlinelibrary.wiley.com/doi/10.1002/adma.202004560" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/adma.202004560</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/adma.202004560" target="_blank" >10.1002/adma.202004560</a>

Result language

angličtina

Original language name

Asymmetric Supercapacitors: Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitors

Original language description

In this work, the covalent attachment of an amine functionalized metal-organic framework (UiO-66-NH2 = Zr6O4(OH)(4)(bdc-NH2)(6); bdc-NH2 = 2-amino-1,4-benzenedicarboxylate) (UiO-Universitetet i Oslo) to the basal-plane of carboxylate functionalized graphene (graphene acid = GA) via amide bonds is reported. The resultant GA@UiO-66-NH2 hybrid displayed a large specific surface area, hierarchical pores and an interconnected conductive network. The electrochemical characterizations demonstrated that the hybrid GA@UiO-66-NH2 acts as an effective charge storing material with a capacitance of up to 651 F g(-1), significantly higher than traditional graphene-based materials. The results suggest that the amide linkage plays a key role in the formation of a p-conjugated structure, which facilitates charge transfer and consequently offers good capacitance and cycling stability. Furthermore, to realize the practical feasibility, an asymmetric supercapacitor using a GA@UiO-66-NH2 positive electrode with Ti3C2TX MXene as the opposing electrode has been constructed. The cell is able to deliver a power density of up to 16 kW kg(-1) and an energy density of up to 73 Wh kg(-1), which are comparable to several commercial devices such as Pb-acid and Ni/MH batteries. Under an intermediate level of loading, the device retained 88% of its initial capacitance after 10 000 cycles.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

21001 - Nano-materials (production and properties)

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2021

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

ADVANCED MATERIALS

ISSN

0935-9648

e-ISSN

—

Volume of the periodical

33

Issue of the periodical within the volume

4

Country of publishing house

DE - GERMANY

Number of pages

10

Pages from-to

"nečíslováno"

UT code for WoS article

000596065400001

EID of the result in the Scopus database

2-s2.0-85097208378