Engineering graphitic carbon nitride (g-C3N4) for catalytic reduction of CO2to fuels and chemicals: Strategy and mechanism

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F21%3A73612344" target="_blank" >RIV/61989592:15640/21:73612344 - isvavai.cz</a>

Result on the web

<a href="https://pubs.rsc.org/en/content/articlelanding/2021/GC/D1GC01303C" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/GC/D1GC01303C</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d1gc01303c" target="_blank" >10.1039/d1gc01303c</a>

Result language

angličtina

Original language name

Engineering graphitic carbon nitride (g-C3N4) for catalytic reduction of CO2to fuels and chemicals: Strategy and mechanism

Original language description

The reduction of carbon dioxide to useful fuels/chemicals, such as methane, formic, and methanol, is an innovative way to address looming energy and environmental issues. Graphitic carbon nitride (g-C3N4), as a greener and low-cost catalyst for the electrocatalytic and photocatalytic carbon dioxide reduction reaction (CO2RR) to provide usable fuels, is endowed with numerous appealing attributes, e.g., Earth-abundant resources, facile synthesis, metal-free nature, catalytic properties, and unique thermal-physical-chemical stability. Articles on the use of g-C3N4 for CO2 transformation have increased significantly in the past decade, and it is important to provide timely updates in this emerging and active research area. This review emphasizes the rational structural engineering of g-C3N4, including doping (i.e., metal, non-metal, and molecular) and heterojunction formation (i.e., metal, metal oxide, metal phosphide, metal hydroxide, metal complex, Ag-halides, and carbon materials) for electrocatalytic, photoelectrocatalytic, and photocatalytic CO2RR. Besides, an in-depth deciphering of the CO2RR mechanism from experimental, theoretical, and fundamental concepts is provided, including deliberation on the sources/emission and strategies to avoid/reduce CO2 emission. Lastly, a brief conclusion and outlook on the challenges and future prospects are highlighted to assist further in the rational design of the g-C3N4-based catalyst as a selective and efficient catalyst for the CO2RR.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

21001 - Nano-materials (production and properties)

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2021

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

GREEN CHEMISTRY

ISSN

1463-9262

e-ISSN

—

Volume of the periodical

23

Issue of the periodical within the volume

15

Country of publishing house

GB - UNITED KINGDOM

Number of pages

35

Pages from-to

5394-5428

UT code for WoS article

000674032000001

EID of the result in the Scopus database

2-s2.0-85112353264