2D Metal–Organic Framework Nanosheets based on Pd-TCPP as Photocatalysts for Highly Improved Hydrogen Evolution
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F24%3A73624532" target="_blank" >RIV/61989592:15640/24:73624532 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/10.1002/anie.202319255" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/anie.202319255</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202319255" target="_blank" >10.1002/anie.202319255</a>
Alternative languages
Result language
angličtina
Original language name
2D Metal–Organic Framework Nanosheets based on Pd-TCPP as Photocatalysts for Highly Improved Hydrogen Evolution
Original language description
In this report, a 2D MOF nanosheet derived Pd single-atom catalyst, denoted as Pd-MOF, was fabricated and examined for visible light photocatalytic hydrogen evolution reaction (HER). This Pd-MOF can provide a remarkable photocatalytic activity (a H2 production rate of 21.3 mmol/gh in the visible range), which outperforms recently reported Pt-MOFs (with a H2 production rate of 6.6 mmol/gh) with a similar noble metal loading. Notably, this high efficiency of Pd-MOF is not due to different chemical environment of the metal center, nor by changes in the spectral light absorption. The higher performance of the Pd-MOF in comparison to the analogue Pt-MOF is attributed to the longer lifetime of the photogenerated electron-hole pairs and higher charge transfer efficiency.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20402 - Chemical process engineering
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN
1433-7851
e-ISSN
1521-3773
Volume of the periodical
63
Issue of the periodical within the volume
7
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
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UT code for WoS article
001142230400001
EID of the result in the Scopus database
2-s2.0-85182487465