Heterogeneous catalyzed N-alkylation of amines with alcohols via borrowing hydrogen methodology

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F25%3A73631033" target="_blank" >RIV/61989592:15640/25:73631033 - isvavai.cz</a>

Alternative codes found

RIV/61989100:27640/25:10257951

Result on the web

<a href="https://www.sciencedirect.com/science/article/pii/S0010854525003200?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0010854525003200?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.ccr.2025.216750" target="_blank" >10.1016/j.ccr.2025.216750</a>

Result language

angličtina

Original language name

Heterogeneous catalyzed N-alkylation of amines with alcohols via borrowing hydrogen methodology

Original language description

The synthesis and functionalization of amines by catalytic N-alkylations using alcohols via the borrowing hydrogen strategy is an environmentally friendly and atom-economical process, in which water is produced as the only by-product. To perform these reactions more efficiently and selectively, the design and applicability of suitable catalysts are prerequisites and of paramount importance. More specifically, heterogeneous catalysts are preferred for the advancement of the amine synthetic process due to the inherited advantages of these materials in terms of stability, recyclability and reusability. In addition, utilizing biomass-derived alcohols as alkylating agents to produce N-alkylated amines is of increasing importance with respect to the valorization of renewable feedstocks, which represent an alternative and potentially competitive approach to fossil-based feedstocks. Herein, we comprehensively review the research progress on the N-alkylation of various amines (e.g., ammonia, primary amines, secondary amines) as well as amides, and sulfonamides with alcohols as potential alkylating agents via the borrowing hydrogen strategy using heterogeneous catalysts under thermal and photochemical conditions. Additionally, synesthetic approaches for catalyst design, reaction mechanism and their structureperformance relationship are discussed. Moreover, advanced in situ characterization and density functional theory (DFT) studies are emphasized to comprehend the reaction pathways and mechanisms involved in the thermocatalytic and photocatalytic N-alkylation of amines with alcohols. Finally, we highlight the current challenges and future opportunities within this attractive field.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

21001 - Nano-materials (production and properties)

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2025

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Coordination Chemistry Reviews

ISSN

0010-8545

e-ISSN

1873-3840

Volume of the periodical

541

Issue of the periodical within the volume

October

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

32

Pages from-to

nestránkováno

UT code for WoS article

001500371100001

EID of the result in the Scopus database

2-s2.0-105005950695