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Conversion of vegetable Oils into Hydrocarbons over CoMo/MCM-41 catalysts

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F10%3A%230000059" target="_blank" >RIV/62243136:_____/10:#0000059 - isvavai.cz</a>

  • Alternative codes found

    RIV/62243136:_____/10:#0000115

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Conversion of vegetable Oils into Hydrocarbons over CoMo/MCM-41 catalysts

  • Original language description

    Deoxygenation of triglycerides over Co and Mo sulfides supported on a series of mesoporous molecular sieves (MCM-41) with varying Si/Al ratio has been investigated in this contribution. The catalysts were tested in a flow reactor at reaction temperatures300 and 320 _C, hydrogen pressures 2?11 MPa and space velocities 1?4 h-1 using refined rapeseed oil as a feedstock. Incorporation of Al into the framework of MCM-41 led to an increase of both conversion of triglycerides and selectivity to hydrocarbons,namely n-heptadecane and n-octadecane. However, the conversion of triglycerides was lower than that achieved over alumina supported CoMo. Moreover, the rather high selectivity to oxygenated products, as compared with alumina supports, has made possible adetailed description of the reaction intermediates and their dependence on the reaction conditions.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/FT-TA3%2F074" target="_blank" >FT-TA3/074: *Utilization of vegetable oils and glycerin for the production of motor fuels.</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Topic in Catalysis

  • ISSN

    1022-5528

  • e-ISSN

  • Volume of the periodical

    2010

  • Issue of the periodical within the volume

    53

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database