Towards understanding the hydrodeoxygenation pathways of furfural?acetone aldol condensation

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F15%3AGACR02CL" target="_blank" >RIV/62243136:_____/15:GACR02CL - isvavai.cz</a>

Result on the web

<a href="http://pubs.rsc.org/en/content/articlelanding/2015/cy/c5cy01422k#!divAbstract" target="_blank" >http://pubs.rsc.org/en/content/articlelanding/2015/cy/c5cy01422k#!divAbstract</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/C5CY01422K" target="_blank" >10.1039/C5CY01422K</a>

Result language

angličtina

Original language name

Towards understanding the hydrodeoxygenation pathways of furfural?acetone aldol condensation

Original language description

Aiming at the valorisation of furfural-derived compounds, the hydrodeoxygenation of furfural?acetone condensation products has been studied using supported platinum catalysts. The influence of the catalytic properties of different supports, such as SiO2,Al2O3, TiO2, hydrotalcite (HTC), Beta zeolite, Al-SBA-15 and WO3?ZrO2, was evaluated in a batch reactor for 480 min at 200 °C and 50 bar of H2. The used feed consisted of a mixture of furfural?acetone adducts (C8?C19), obtained in previous experiments using a continuous flow reactor and hydrotalcite as a catalyst. Except for Pt/SiO2, all catalysts showed high conversion of the reactants, especially due to the hydrogenation of all the aliphatic C[double bond, length as m-dash]C bonds. However, the extent of further hydrogenation (furan C[double bond, length as m-dash]C and ketone C[double bond, length as m-dash]O bonds) was limited, particularly when HTC and Al2O3 were used as supports. The higher accessibility of Pt/TiO2 and the smalle

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/GBP106%2F12%2FG015" target="_blank" >GBP106/12/G015: Intelligent design of nanoporous adsorbents and catalysts</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Catalysis Science & Technology

ISSN

2044-4753

e-ISSN

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Volume of the periodical

6

Issue of the periodical within the volume

6

Country of publishing house

GB - UNITED KINGDOM

Number of pages

13

Pages from-to

1829-1841

UT code for WoS article

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EID of the result in the Scopus database

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