Unprecedented selectivities in aldol condensation over Mg?Al hydrotalcite in a fixed bed reactor setup

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F15%3AGACR06CL" target="_blank" >RIV/62243136:_____/15:GACR06CL - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S1566736714003501" target="_blank" >http://www.sciencedirect.com/science/article/pii/S1566736714003501</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.catcom.2014.09.002" target="_blank" >10.1016/j.catcom.2014.09.002</a>

Result language
angličtina
Original language name
Unprecedented selectivities in aldol condensation over Mg?Al hydrotalcite in a fixed bed reactor setup
Original language description
Aldol condensation of furfural with acetone (molar ratio 1:10) was carried out in a flow fixed bed setup at 50 °C using calcined hydrotalcite with Mg/Al of 3 as a catalyst. Complete conversion of furfural and stable catalyst performance was obtained during the initial 50 h on stream. This period was followed by a rapid catalyst deactivation. In contrast to previous reports, higher molecular weight products that were identified as products of successive aldol condensation of acetone with furfural were observed. Their concentration was time-dependent with a maximum formation after 10 to 30 h on stream
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GBP106%2F12%2FG015" target="_blank" >GBP106/12/G015: Intelligent design of nanoporous adsorbents and catalysts</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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