Mechanistic insights into the hydroconversion of cinnamaldehyde using mechanochemically-synthesized Pd/Al-SBA-15 catalysts
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F15%3AMPO04CL" target="_blank" >RIV/62243136:_____/15:MPO04CL - isvavai.cz</a>
Result on the web
<a href="http://pubs.rsc.org/en/content/articlelanding/2015/gc/c4gc01354a/unauth#!divAbstract" target="_blank" >http://pubs.rsc.org/en/content/articlelanding/2015/gc/c4gc01354a/unauth#!divAbstract</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/C4GC01354A" target="_blank" >10.1039/C4GC01354A</a>
Alternative languages
Result language
angličtina
Original language name
Mechanistic insights into the hydroconversion of cinnamaldehyde using mechanochemically-synthesized Pd/Al-SBA-15 catalysts
Original language description
The hydroconversion of cinnamaldehyde as an ?,?-unsaturated compound was studied using a simple and efficient hydrogen-donating protocol catalyzed by mechanochemically synthesized bifunctional Pd/Al-SBA-15 catalysts. Materials were characterized using TGA-TDA, nitrogen physisorption, TEM and EDX analyses. Catalytic results pointed to the presence of competitive pathways that are able to provide a selectivity switch from the expected fully hydrogenated aromatic ring (e.g. cyclohexane) and hydrogenated products (e.g. hydrocinnamaldehyde, cinnamyl alcohol and 3-phenylpropan-1-ol) to the unexpected ethylbenzene and oxalic acid products from hydrodeformylation and hydrocarboxylation reactions of cinnamaldehyde and formic acid, respectively.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/FR-TI3%2F316" target="_blank" >FR-TI3/316: *Research and development of highly active catalyst based on ZrO2 and its application for izomerization of C5-C6 hydrocarbons</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Green Chemistry
ISSN
1463-9270
e-ISSN
—
Volume of the periodical
17
Issue of the periodical within the volume
1
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
565-572
UT code for WoS article
—
EID of the result in the Scopus database
—