(V)/Hydrotalcite, (V)/Al2O3, (V)/TiO2 and (V)/SBA-15 catalysts for the partial oxidation of ethanol to acetaldehyde

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F16%3AN0000007" target="_blank" >RIV/62243136:_____/16:N0000007 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S1381116916301649" target="_blank" >http://www.sciencedirect.com/science/article/pii/S1381116916301649</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molcata.2016.04.024" target="_blank" >10.1016/j.molcata.2016.04.024</a>

Result language
angličtina
Original language name
(V)/Hydrotalcite, (V)/Al2O3, (V)/TiO2 and (V)/SBA-15 catalysts for the partial oxidation of ethanol to acetaldehyde
Original language description
Vanadium-based catalysts have been investigated in the partial oxidation of ethanol to acetaldehyde with the aim of understanding relationship between vanadium structure and acetaldehyde productivity. Hydrotalcite, Al2O3, TiO2 and SBA-15 with and without a 5% of vanadium content were prepared to study the oxidative dehydrogenation of ethanol. They were characterized by XRF, TPR (H2), NH3-TPD, CO2-TPD, RAMAN, UV-vis, Nitrogen physisorption, XRD and SEM. The most easily reducible catalysts (as determined by TPR) were the most active ones. In the low temperature region (150 °C), the most active catalyst was the V/TiO2 which presented stable activity in the production of acetaldehyde up to TOS = 200 h. On the contrary, in the high temperature region (250 °C), the most active catalyst was the V/Al2O3catalyst. The most promising result was obtained over V/TiO2 catalyst that afforded a total ethanol conversion of 60.4%wt. and a selectivity to acetaldehyde of 76.2%wt. at TOS = 164 h and T = 150 °C. Also, hydrotalcite was tested for the first time for this type of reaction providing a conversion lower than 7%wt. with a selectivity of 100%wt. to acetaldehyde at T = 150–225 °C.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA15-19780S" target="_blank" >GA15-19780S: The investigation of the active sites in supported vanadia catalysts for the selective oxidation of ethanol</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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