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Hydrotreatment co-processing of atmospheric gasoil with triglycerides over supported MoCx and MoNx catalysts

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F18%3AN0000033" target="_blank" >RIV/62243136:_____/18:N0000033 - isvavai.cz</a>

  • Result on the web

    <a href="http://www.slsz.cz/icct2018/START.htm" target="_blank" >http://www.slsz.cz/icct2018/START.htm</a>

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Hydrotreatment co-processing of atmospheric gasoil with triglycerides over supported MoCx and MoNx catalysts

  • Original language description

    Poster presentation for ICCT conference in Mikulov. The most common way to produce renewable diesel is transesterification of triglycerides to produce FAME (Fatty acid methyl ester). However, advanced biofuels can be produced by co-processing of these triglycerides with middle distillates and some other petroleum fractions in refinery hydrotreating units. The main advantages are better quality and stability in comparison with FAME. The co-processing involves the sulphur and nitrogen removal from middle distillates, as well as the oxygen from the triglyceride component. The hydrotreatment of vegetable oil produces HVO (Hydrotreated Vegetable oil), containing mainly linear hydrocarbons (nC15-18), light gases, (C3H8, CH4 and COx) and water. The conventional catalysts for HDS (hydrodesulphurization) in refineries are sulphided catalysts with Mo or W as active metals, and Ni or Co as promotors. The most common catalyst support is Al2O3. To avoid decrease of HDS efficiency and reactor overheating during co-processing, only limited concentration of vegetable oil can be used. Sulphur free catalysts as molybdenum carbide or nitride represent a promising alternative to resolve the problem of the catalyst HDS activity in the presence of vegetable oils.

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

  • OECD FORD branch

    20402 - Chemical process engineering

Result continuities

  • Project

    <a href="/en/project/LO1606" target="_blank" >LO1606: Development of the UniCRE centre</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů