Kinetic and Thermodynamic Analysis of Guaiacol Hydrodeoxygenation

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F19%3AN0000022" target="_blank" >RIV/62243136:_____/19:N0000022 - isvavai.cz</a>
Result on the web
<a href="https://link.springer.com/content/pdf/10.1007/s10562-019-02856-x.pdf" target="_blank" >https://link.springer.com/content/pdf/10.1007/s10562-019-02856-x.pdf</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10562-019-02856-x" target="_blank" >10.1007/s10562-019-02856-x</a>

Result language
angličtina
Original language name
Kinetic and Thermodynamic Analysis of Guaiacol Hydrodeoxygenation
Original language description
Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported MoxC–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 C and 300 C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo2C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
20402 - Chemical process engineering

Project
<a href="/en/project/LO1606" target="_blank" >LO1606: Development of the UniCRE centre</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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