Fischer–Tropsch synthesis, the effect of promoters, catalyst support, and reaction conditions selection

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F20%3AN0000038" target="_blank" >RIV/62243136:_____/20:N0000038 - isvavai.cz</a>

Result on the web

<a href="https://doi.org/10.1007/s00706-020-02590-w" target="_blank" >https://doi.org/10.1007/s00706-020-02590-w</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s00706-020-02590" target="_blank" >10.1007/s00706-020-02590</a>

Result language

angličtina

Original language name

Fischer–Tropsch synthesis, the effect of promoters, catalyst support, and reaction conditions selection

Original language description

This work brings the overview of Fischer–Tropsch synthesis (FTS) from catalysis point of view. The role of promoters’ type and their amount loaded into the catalyst are described and discussed for both, iron- (Cu, K, Na, S, Zr, Ni) and cobalt (Ru, Pt, Re, Zr, Ag, Rh, Ir, Au)-based catalysts, respectively, as same as the role of catalyst supports and reaction conditions. Catalyst supports discussed in this work are from the group of oxides, mesoporous silicas and zeolites, carbon-based materials, and carbides. Reaction conditions studied and discussed are reaction temperature, gas hourly space velocity of syngas and hydrogen to carbon monoxide ratio in syngas and reaction pressure. For iron-based catalysts, reaction temperature is discussed in the range of 508–613 K, while for cobalt types in the range of 468–513 K. Reaction pressure is discussed for both catalyst types up to 3 MPa. All the parameters are presented and discussed using FTS selectivity to main groups of products, such as CH4, CO2, C2– C4 hydrocarbons, and C5+ hydrocarbons together with syngas conversion degree. Detailed review of data published in articles studying FTS over iron and cobalt catalysts supplied large data set for presenting and discussion of trends and effects of aimed parameters and for their visualization in form of set of charts. This data analysis brings complex overview of basic trends of catalytic properties of cobalt and iron catalysts.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

20400 - Chemical engineering

Project

<a href="/en/project/LM2018119" target="_blank" >LM2018119: Catalytic processes for efficient utilization of carbonaceous energy raw materials</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2020

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Monatshefte für Chemie - Chemical Monthly

ISSN

0026-9247

e-ISSN

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Volume of the periodical

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Issue of the periodical within the volume

151

Country of publishing house

CH - SWITZERLAND

Number of pages

26

Pages from-to

649-675

UT code for WoS article

000531850900001

EID of the result in the Scopus database

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