Mechanochemical Synthesis of Nickel-Modified Metal–Organic Frameworks for Reduction Reactions

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F21%3AN0000010" target="_blank" >RIV/62243136:_____/21:N0000010 - isvavai.cz</a>

Result on the web

<a href="https://www.mdpi.com/2073-4344/11/5/526" target="_blank" >https://www.mdpi.com/2073-4344/11/5/526</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal11050526" target="_blank" >10.3390/catal11050526</a>

Result language

angličtina

Original language name

Mechanochemical Synthesis of Nickel-Modified Metal–Organic Frameworks for Reduction Reactions

Original language description

In this work, we report the incorporation of nickel oxide nanoparticles into a metal–organic framework (MOF) structure by a solvent-free mechanochemical strategy. In particular, the irconiumbased MOF UiO-66 was modified with different Ni loadings and characterized using complementary techniques including X-ray diffraction (XRD), N2 porosimetry and X-ray photoelectron spectroscopy (XPS). The catalytic potential of the as-prepared Ni/UiO-66 materials in the hydrogenation reaction of methyl levulinate using 2-propanol as hydrogen donor solvent has been investigated under flow conditions. Under optimized conditions, the 5%Ni/UiO-66 led to the best catalytic performance (70% yield, 100% selectivity to gamma-valerolactone), which could be attributed to the higher content of the Ni species within the MOF structure. The obtained results are promising and contribute to highlighting the great potential of MOFs in biomass upgrading processes, opening the path to the sustainable development of the chemical industry.

Czech name

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Czech description

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Type

J_SC - Article in a specialist periodical, which is included in the SCOPUS database

CEP classification

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OECD FORD branch

20400 - Chemical engineering

Project

<a href="/en/project/LM2018119" target="_blank" >LM2018119: Catalytic processes for efficient utilization of carbonaceous energy raw materials</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2021

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Catalysts

ISSN

2073-4344

e-ISSN

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Volume of the periodical

11

Issue of the periodical within the volume

526

Country of publishing house

CH - SWITZERLAND

Number of pages

10

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

2-s2.0-85104448267