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Regeneration of exhausted adsorbents after PFAS adsorption: A critical review

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F24%3AN0000023" target="_blank" >RIV/62243136:_____/24:N0000023 - isvavai.cz</a>

  • Alternative codes found

    RIV/49777513:23420/24:43972943

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0304389424010082?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0304389424010082?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jhazmat.2024.134429" target="_blank" >10.1016/j.jhazmat.2024.134429</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Regeneration of exhausted adsorbents after PFAS adsorption: A critical review

  • Original language description

    The adsorption process efficiently removes per- and polyfluoroalkyl substances (PFAS) from water, but managing exhausted adsorbents presents notable environmental and economic challenges. Conventional disposal methods, such as incineration, may reintroduce PFAS into the environment. Therefore, advanced regeneration techniques are imperative to prevent leaching during disposal and enhance sustainability and cost-effectiveness. This review critically evaluates thermal and chemical regeneration approaches for PFAS-laden adsorbents, elucidating their operational mechanisms, the influence of water quality parameters, and their inherent advantages and limitations. Thermal regeneration achieves notable desorption efficiencies, reaching up to 99% for activated carbon. However, it requires significant energy input and risks compromising the adsorbent’s structural integrity, resulting in considerable mass loss (10–20%). In contrast, chemical regeneration presents a diverse efficiency landscape across different regenerants, including water, acidic/basic, salt, solvent, and multi-component solutions. Multi-component solutions demonstrate superior efficiency (>90%) compared to solvent-based solutions (12.50%), which, in turn, outperform salt (2.34%), acidic/basic (1.17%), and water (0.40%) regenerants. This hierarchical effectiveness underscores the nuanced nature of chemical regeneration, significantly influenced by factors such as regenerant composition, the molecular structure of PFAS, and the presence of organic cocontaminants. Exploring the conditional efficacy of thermal and chemical regeneration methods underscores the imperative of strategic selection based on specific types of PFAS and material properties. By emphasizing the limitations and potential of particular regeneration schemes and advocating for future research directions, such as exploring persulfate activation treatments, this review aims to catalyze the development of more effective regeneration processes. The ultimate goal is to ensure water quality and public health protection through environmentally sound solutions for PFAS remediation efforts.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20400 - Chemical engineering

Result continuities

  • Project

  • Continuities

    V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Hazardous Materials

  • ISSN

    0304-3894

  • e-ISSN

    1873-3336

  • Volume of the periodical

    2024

  • Issue of the periodical within the volume

    471

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    22

  • Pages from-to

    nestrankovano

  • UT code for WoS article

    001237407100001

  • EID of the result in the Scopus database

    2-s2.0-85191440044