Structure and spectroscopy of diorganotin(IV) complexes derived from N''-(2-hydroxy-3-methoxybenzylidene)benzohydrazide

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62690094%3A18470%2F11%3A43866562" target="_blank" >RIV/62690094:18470/11:43866562 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.poly.2011.06.036" target="_blank" >http://dx.doi.org/10.1016/j.poly.2011.06.036</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.poly.2011.06.036" target="_blank" >10.1016/j.poly.2011.06.036</a>

Result language

angličtina

Original language name

Structure and spectroscopy of diorganotin(IV) complexes derived from N''-(2-hydroxy-3-methoxybenzylidene)benzohydrazide

Original language description

Three new diorganotin(IV) complexes of the general formula R2Sn[3-(OMe)-2-OC6H3CH=N?N=C(O)Ph] (R = Ph, Ia; R = Me, Ib; R = n-Bu, Ic) have been synthesised from the corresponding diorganotin(IV) dichlorides and the ligand, N0-(2-hydroxy-3-methoxybenzylidene)benzohydrazide in methanol at room temperature in the presence of trimethylamine. All the complexes have been characterized by elemental analysis, IR and 1H, 13C, 15N, 119Sn NMR spectra, and their structures have been confirmed by single crystal X-raydiffraction analysis of one representative compound Ia. Complex Ia crystallises in the orthorhombic system, space group Pna21 with a = 12.424(5), b = 9.911(5), c = 18.872(5) A; Z = 4. The ligand N0-(2-hydroxy-3-methoxybenzylidene)benzohydrazide (H2L) coordinates to the metal centre in the enolate form via the phenolic O, imino N and enolic O atoms. In Ia, the central tin atom adopts a distorted trigonal bipyramidal coordination geometry with the oxygen atoms in axial positions, while th

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

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Continuities

V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

30

Issue of the periodical within the volume

15

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

6

Pages from-to

2544-2549

UT code for WoS article

000295435000017

EID of the result in the Scopus database

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