Perspectives on the Role of the Frontier Effective-for-Reaction Molecular Orbital (FERMO) in the Study of Chemical Reactivity: An Updated Review

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62690094%3A18470%2F20%3A50016832" target="_blank" >RIV/62690094:18470/20:50016832 - isvavai.cz</a>

Result on the web

<a href="https://www.ingentaconnect.com/contentone/ben/coc/2020/00000024/00000003/art00005" target="_blank" >https://www.ingentaconnect.com/contentone/ben/coc/2020/00000024/00000003/art00005</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.2174/1385272824666200204121044" target="_blank" >10.2174/1385272824666200204121044</a>

Result language

angličtina

Original language name

Perspectives on the Role of the Frontier Effective-for-Reaction Molecular Orbital (FERMO) in the Study of Chemical Reactivity: An Updated Review

Original language description

Molecular orbitals are critical in the rationalization of several chemical reactions. Thus, the frontier molecular orbital theory, proposed by Fukui&apos;s group, postulated the importance of the Highest Occupied Molecular Orbital (HOMO) and the Lowest Unoccupied Molecular Orbital (LUMO) for chemical reactions. It should be kept in mind, however, that there are limitations of this theory and new perspectives about the chemical reactivity have recently been arisen based on composition and location of other frontier molecular orbitals. In this review, we have reported the development and the most recent applications of the Frontier Effective-for-Reaction Molecular Orbital (FERMO) concept, which describes the breaking and formation of new chemical bonds and can in turn, provide important clues that modulate chemical reactivity of atoms and molecules.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10401 - Organic chemistry

Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2020

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Current organic chemistry

ISSN

1385-2728

e-ISSN

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Volume of the periodical

24

Issue of the periodical within the volume

3

Country of publishing house

AE - UNITED ARAB EMIRATES

Number of pages

18

Pages from-to

314-331

UT code for WoS article

000532049200004

EID of the result in the Scopus database

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