Nano-Ru Supported on Ni Nanowires for Low-Temperature Carbon Dioxide Methanation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62690094%3A18470%2F20%3A50017093" target="_blank" >RIV/62690094:18470/20:50017093 - isvavai.cz</a>
Result on the web
<a href="https://www.mdpi.com/2073-4344/10/5/513/pdf" target="_blank" >https://www.mdpi.com/2073-4344/10/5/513/pdf</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/catal10050513" target="_blank" >10.3390/catal10050513</a>
Alternative languages
Result language
angličtina
Original language name
Nano-Ru Supported on Ni Nanowires for Low-Temperature Carbon Dioxide Methanation
Original language description
In this study, we investigated the catalytic performance of Ru nanoparticles (NPs) supported on Ni-nanowires for the first time. This appears to be a highly efficient catalyst for low-temperature methanation, e.g., ca. 100% conversion and 100% of CH(4)selectivity can be achieved at ca. 179 degrees C, while the turnover frequency (TOF) value was 2479.2 h(-1). At the same time, the onset of a reaction was observed at a temperature as low as 130 degrees C. The comparison of nano-Pd and nano-Ru supported on Ni-nanowires enabled us to prove that oxidized surface metals are highly important for the high activity of the investigated nano-Ru@nanowired-Ni. Moreover, similar to the microscopic Sabatier rule, which indicates that some optimal reactivity level of a catalyst exists, we showed that Ni-nanowires (a higher specific surface area than a standard metal surface, e.g., in the form of a metal foam, but lower than nano-sized materials) significantly enhances the performance of the Ru-Ni catalytic system.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
CATALYSTS
ISSN
2073-4344
e-ISSN
—
Volume of the periodical
10
Issue of the periodical within the volume
5
Country of publishing house
CH - SWITZERLAND
Number of pages
14
Pages from-to
"Article Number: 513"
UT code for WoS article
000546007000069
EID of the result in the Scopus database
2-s2.0-85084835739