SbI3 center dot 3S(8): A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62690094%3A18470%2F23%3A50020226" target="_blank" >RIV/62690094:18470/23:50020226 - isvavai.cz</a>
Result on the web
<a href="https://www.mdpi.com/1996-1944/16/3/1105" target="_blank" >https://www.mdpi.com/1996-1944/16/3/1105</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/ma16031105" target="_blank" >10.3390/ma16031105</a>
Alternative languages
Result language
angličtina
Original language name
SbI3 center dot 3S(8): A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation
Original language description
In the past twenty years, the basic investigation of innovative Non-Linear Optical (NLO) crystals has received significant attention, which has built the crucial heritage for the use of NLO materials. Fundamental research is essential given the scarcity of materials for NLO compounds, especially in the deep ultraviolet (DUV) and middle- and far-infrared (MFIR) regions. In the present work, we synthesized high-quality MFIR SbI3 center dot 3S(8) NLO crystals having a length in the range of 1-5 mm through rapid facile liquid phase ultrasonic reaction followed by the assistance of instantaneous natural evaporation phenomenon of the solvent at room temperature. X-ray diffraction (XRD) results ratify the hexagonal R3m structure of SbI3 center dot 3S(8) crystal, and energy-dispersive X-ray spectroscopy (EDX) demonstrates that the elemental composition of SbI3 center dot 3S(8) crystal is similar to that of its theoretical composition. The direct and indirect forbidden energy gaps of SbI3 center dot 3S(8) were measured from the optical transmittance spectra and they were shown to be 2.893 eV and 1.986 eV, respectively. The green sparkling signal has been observed from the crystal during the second harmonic generation (SHG) experiment. Therefore, as inorganic adducts are often explored as NLO crystals, this work on the MFIR SbI3 center dot 3S(8) NLO crystal can bring about additional investigations on this hot topic in the near future.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20501 - Materials engineering
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
MATERIALS
ISSN
1996-1944
e-ISSN
1996-1944
Volume of the periodical
16
Issue of the periodical within the volume
3
Country of publishing house
CH - SWITZERLAND
Number of pages
12
Pages from-to
"Article Number: 1105"
UT code for WoS article
000932787300001
EID of the result in the Scopus database
2-s2.0-85147852904