Concentrations of platinum-group elements (PGE), Re and Au in arsenian pyrite and millerite from Mo–Ni–PGE-Au black shales (Zunyi region, Guizhou Province, China): results from LA-ICPMS study

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985831%3A_____%2F17%3A00479341" target="_blank" >RIV/67985831:_____/17:00479341 - isvavai.cz</a>

Alternative codes found

RIV/00025798:_____/17:00000124

Result on the web

<a href="http://dx.doi.org/10.1127/ejm/2017/0029-2640" target="_blank" >http://dx.doi.org/10.1127/ejm/2017/0029-2640</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1127/ejm/2017/0029-2640" target="_blank" >10.1127/ejm/2017/0029-2640</a>

Result language

angličtina

Original language name

Concentrations of platinum-group elements (PGE), Re and Au in arsenian pyrite and millerite from Mo–Ni–PGE-Au black shales (Zunyi region, Guizhou Province, China): results from LA-ICPMS study

Original language description

Lower Cambrian Mo–Ni sulphidic black shales from the Huangjiawan mine (Guizhou Province, south China) have anomalous platinum-group element (PGE) concentrations (up to ca 1 ppm in total). We used LA-ICPMS to study the distribution of PGE in pyrite and Ni-sulphide (millerite) and FE-SEM/EDS for determination of As in pyrite. A sulphide concentrate was produced by innovative hydroseparation techniques from one representative sample, which contained 162 ppb Pt, 309 ppb Pd, 12.2 ppb Ru, 11.3 ppb Rh, 1.5 ppb Ir, 11 212 ppb Re and 343 ppb Au. Mineralogical analysis revealed that pyrite forms ca 12 vol%, which corresponds to a calculated ca 18.4 wt% of all mineral phases in mineralized black shale. We found that pyrite contains on average (144 analyses) 0.10 ppm Pt, 0.11 ppm Re and 1.40 ppm Au (Ru, Rh, Pd, Os and Ir were below detection limit). It also contains from ca 0.5 to ca 1.8 wt% As and can be therefore classified as arsenian pyrite. Millerite (77 analyses) showed PGE, Re and Au values below detection limit. We suggest that pyrite represents a dominant Au carrier, containing between 64 and 83% Au of the total Au mineralised rock budget. Conversely, pyrite does not bear any significant amount of Re and Pt, contributing up to ca 0.2% and ca 12.5% to their whole rock budgets, respectively. Time resolved LA-ICPMS spectra in pyrite indicate that Pt, Re and Au behave as typical lattice-bound elements, with only Re locally forming micro-inclusions. Arsenic is heterogeneously distributed in pyrite and the Au/As ratio (much lower than 0.02) is in support of Au to be structurally bound in solid solution.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10505 - Geology

Project

<a href="/en/project/GA13-15390S" target="_blank" >GA13-15390S: Re-Os geochronology of ore mineralizations from the Bohemian Massif with possible metallogenic implications</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2017

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

European Journal of Mineralogy

ISSN

0935-1221

e-ISSN

—

Volume of the periodical

29

Issue of the periodical within the volume

4

Country of publishing house

DE - GERMANY

Number of pages

11

Pages from-to

623-633

UT code for WoS article

000426885400009

EID of the result in the Scopus database

2-s2.0-85031301670