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Diversity of lithium mica compositions in mineralized granite-greisen system: Cinovec Li-Sn-W deposit, Erzgebirge

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985831%3A_____%2F19%3A00503969" target="_blank" >RIV/67985831:_____/19:00503969 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216224:14310/19:00107248 RIV/00216305:26310/19:PU133150

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0169136818304268?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0169136818304268?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.oregeorev.2019.01.013" target="_blank" >10.1016/j.oregeorev.2019.01.013</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Diversity of lithium mica compositions in mineralized granite-greisen system: Cinovec Li-Sn-W deposit, Erzgebirge

  • Original language description

    The Li-Sn-W deposit Cínovec/Zinnwald in the eastern Erzgebirge (Czech Republic and Germany) represents one of the worldwide best known examples of complex rare-metal plutons with pervasive greisenization. Mica from altogether 38 samples representing all granite and greisen varieties from the present surface to the depth of 1596 m was analysed using electron microprobe (EMPA) and laser-ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) for major (including F, Rb) and trace (Li, Sc, Ga, Ge, Nb, In, Sn, Cs, Ta, Tl, W) elements, respectively. All primary micas at Cínovec are trioctahedral Li-Fe micas close to the annite–zinnwaldite–trilithionite series. Biotite from granites in the deeper part of the pluton (depth of 735–1596 m) contains 33.9–39.6 wt% SiO2 , 19.6–23.8 wt% FeO, 0.5–0.7 wt% Rb2O, 0.9–1.8 wt% Li2O, 3.4–4.8 wt% F, 381–937 ppm Nb, 34–134 ppm Ta, 20–46 ppm W, and 93–617 ppm Sn. Zinnwaldite from granites in the upper part of the pluton (depth of 0–735 m) contains 41.2–48.5 wt% SiO2, 8.9–15.2 wt% FeO, 0.9–1.9 wt% MnO, 2.0–4.4 wt% Li2 O, 0.8–1.9 wt% Rb2O, 7.0–8.6 wt% F, 43–464 ppm Nb, 101–213 ppm Sn, 6–80 ppm Ta, and 28–52 ppm W. Zinnwaldite from bodies of pervasive greisen and quartz-zinnwaldite veins is, compared to zinnwaldite from granites, relatively slightly enriched in Si, Mn and Ga, and depleted in Fe, F, Rb, Sn, W and Nb. Li and Ta contents are similar. Contents of Li, Rb and F, and the Fe/Mn and Nb/Ta values in mica closely positively correlate with those in the bulk rock, illustrating an upwards fractionation of parental melt. In contrast, the contents of high-field-strength elements in mica do not correspond to their contents in the bulk rock (melt): they were controlled by the order of crystallization of mica vs. accessory oxide minerals. Therefore, biotite generally contains distinctly higher Sn, Nb, Ta, and W than zinnwaldite. Dioctahedral micas of the muscovite–phengite series were found only as a late product of alteration of primary trioctahedral mica. Replacement of greisen-stage zinnwaldite by muscovite is chemically expressed in a strong depletion in Fe, F, and Li, and an enrichment in Sn. The share of trioctahedral mica in the bulk-rock budget of Sn decreases from 40–70% in biotite granite to less than 5% in greisen, in the case of Nb and Ta from 20–50% to less than 10%. The share of mica in the budget of W, mostly in the range of 2–15%, is stable through the whole pluton.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10504 - Mineralogy

Result continuities

  • Project

    <a href="/en/project/GA14-13600S" target="_blank" >GA14-13600S: Rock Textures and Mineral Zoning: Insights into Open System Processes in Granitoides</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Ore Geology Reviews

  • ISSN

    0169-1368

  • e-ISSN

  • Volume of the periodical

    106

  • Issue of the periodical within the volume

    MAR 2019

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    16

  • Pages from-to

    12-27

  • UT code for WoS article

    000462105000002

  • EID of the result in the Scopus database

    2-s2.0-85060554808