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Kinetics of Conversion of High-Level Waste to Glass.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F00%3A27020074" target="_blank" >RIV/67985858:_____/00:27020074 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Kinetics of Conversion of High-Level Waste to Glass.

  • Original language description

    The kinetics of the conversion of high-level waste (HLW) feed to glass controls the rate of HLW processing. Simulated HLW feed and low silicaůhigh sodium (LSHS) feed with co-precipitated Fe, Ni, Cr, and Mn hydroxides (to simulate the chemical and physical makeup of these components in the melter feed) were heated at constant temperature-increase rates (0.4, 4, and 14 C/min), quenched at different stages of conversion, and analyzed with optical microscope, scanning electron microscope, and x-ray diffraction (XRD). Quartz, sodium nitrate, carnegieite [Na8Al4Si4O18], sodalite [Na8(AlSiO4)6(NO2)2], and spinel were identified in the samples. Mass fractions of these phases were determined as functions of the temperature and the heating rate. The fractions ofnitrates and quartz decreased with increasing temperature, starting above 550 C and dropping to zero at 850 C. Spinel was present in the feed within the temperature interval from 350 C to 1050 C, peaking between 550 C and 700 C. Sodalite

  • Czech name

  • Czech description

Classification

  • Type

    C - Chapter in a specialist book

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2000

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Book/collection name

    Nuclear Site Remediation.

  • ISBN

    0-8412-3718-2

  • Number of pages of the result

    15

  • Pages from-to

    314-328

  • Number of pages of the book

  • Publisher name

    American Chemical Society

  • Place of publication

    N/A

  • UT code for WoS chapter