Carbon-Supported Mo Catalysts Prepared by a New Impregnation Method Using a MoO3/Water Slurry: Saturated Loading, Hydrodesulfurization Activity and Promotion by Co.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F01%3A27013063" target="_blank" >RIV/67985858:_____/01:27013063 - isvavai.cz</a>

Result on the web

—

DOI - Digital Object Identifier

—

Result language

angličtina

Original language name

Carbon-Supported Mo Catalysts Prepared by a New Impregnation Method Using a MoO3/Water Slurry: Saturated Loading, Hydrodesulfurization Activity and Promotion by Co.

Original language description

MoO3/activated carbon catalysts were prepared by a new impregnation method: Mo species were adsorbed from a MoO3/water slurry. The maximum achieved loading was 27-34 wt.% MoO3, for various carbons and the deposited phase was X-ray amorphous. The surfacearea and volume of micropores of the carbon supports dropped by about 40% after saturation of the supports with molybdenum trioxide. For the support Norit RX, the point of zero charge decreased from an initial 8.2 to about 2.6 as the MoO3 loading increased up to about 15% and then levelled off. The catalytic activity for the hydrodesulfurization of thiophene increased linearly with loading up to about 15% and then almost levelled off. A strong synergistic affect in activity was achieved by addition of Co to the 15% MoO3/C catalyst; however, the sznergism observed when adding Co to a saturated 33% MoO3/C catalyst was small. It was concluded that molybdenum trioxide is chemisorbed in a highly dispersed 'monolayer' form up to a loading of

Czech name

—

Czech description

—

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CI - Industrial chemistry and chemical engineering

OECD FORD branch

—

Project

<a href="/en/project/IAA4072802" target="_blank" >IAA4072802: Heterogeneous catalysts and catalysts precursors of monolayer type: new type of synthesis by "Slurry impregnation method"</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Carbon

ISSN

—

e-ISSN

—

Volume of the periodical

39

Issue of the periodical within the volume

13

Country of publishing house

GB - UNITED KINGDOM

Number of pages

12

Pages from-to

2023-2034

UT code for WoS article

—

EID of the result in the Scopus database

—