Trimethylsilyl Group Migrations in Cryogenic Ozonolysis of Trimethylsilylethene: Evidence for Nonconcerted Primary Ozonide Decomposition Pathway.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F01%3A27013118" target="_blank" >RIV/67985858:_____/01:27013118 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Trimethylsilyl Group Migrations in Cryogenic Ozonolysis of Trimethylsilylethene: Evidence for Nonconcerted Primary Ozonide Decomposition Pathway.

Original language description

The identification of trimethylsiloxy-1,2-dioxetane and 2-trimethylsilyloperoxyacetaldehyde and assignment of trimethylsiloxymethyl formate as products of the low-temperature ozonolysis of trimethylsilylethene demonstrate feasibility of migrations of trimethylsilyl group in a dioxygen-centered (oxyperoxy) diradical produced via a homolytic cleavage of each of both O-O bonds in the primary ozonide. The results provide the first experimental evidence on the nonconcerted decomposition of the primary ozonide.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CH - Nuclear and quantum chemistry, photo chemistry

OECD FORD branch

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Project

<a href="/en/project/GA104%2F96%2F0472" target="_blank" >GA104/96/0472: Studies of atmospheric chemistry and pollution</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Organic Chemistry

ISSN

0022-3263

e-ISSN

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Volume of the periodical

66

Issue of the periodical within the volume

21

Country of publishing house

US - UNITED STATES

Number of pages

5

Pages from-to

6977-6981

UT code for WoS article

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EID of the result in the Scopus database

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