Temperature Dependence of Excess Molar Volumes of (Heptane + 1-Chloroalkane).

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F02%3A27020251" target="_blank" >RIV/67985858:_____/02:27020251 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Temperature Dependence of Excess Molar Volumes of (Heptane + 1-Chloroalkane).

Original language description

The densities of (heptane + 1-chlorobutane, or 1-chloropentane, or 1-chlorohexane) were measured at the temperatures (308.15, 318.15, and 328.15) K by means of a vibrating-tube densimeter. The excess molar volumes, VmE, calculated from the density data,along with our previous data determined at T=298.15 K for the same systems, provide the temperature dependence of VmE in the temperature range of 298 to 328 K. The VmE results were correlated using the fourth-order Redlich-Kister equation, with the maximum likelihood principle applied for the determination of the adjustable parameters. It was found that the deviations from ideal behaviour (both positive and negative) in the systems studied increase with increasing temperature. .

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F00%2F0600" target="_blank" >GA203/00/0600: Description of thermodynamics properties of fluids at superambient conditions by the methods of applied statistical mechanics</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2002

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Chemical Thermodynamics

ISSN

0021-9614

e-ISSN

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Volume of the periodical

34

Issue of the periodical within the volume

9

Country of publishing house

GB - UNITED KINGDOM

Number of pages

9

Pages from-to

1387-1395

UT code for WoS article

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EID of the result in the Scopus database

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