Diphosphinoazine Rhodium(I) and Iridium(I) Complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F06%3A00049450" target="_blank" >RIV/67985858:_____/06:00049450 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/06:10720
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Diphosphinoazine Rhodium(I) and Iridium(I) Complexes
Original language description
The first rhodium complexes of diphosphinoazines [{RhCl(1,2-h:5,6-h- CH=CHCH2CH2CH=CHCH2CH2 )}2{m-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units.
Czech name
Difosfinoazinové komplexy rhodia(I) a iridia(I)
Czech description
Štěpením můstku chloro(cyclookta-1,5-dien)rhodného dimeru byly připraveny první komplexy rhodia s difosfinoaziny [{RhCl(1,2-h:5,6-h- CH=CHCH2CH2CH=CHCH2CH2 )}2{m-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri), poprvé byly rovněž připraveny analogické komplexy iridia. Rentgenovou difrakcí byly určeny struktury isostrukturních rhodných a iridných komplexů s bis(dicyklohexylfosfino)pinakolonazinem. Difosfinoazinové ligandy v komplexech zůstávají v (Z,Z) konfiguraci a můstkují dvě RhCl(C8H12) jednotky.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2006
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Collection of Czechoslovak Chemical Communications
ISSN
0010-0765
e-ISSN
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Volume of the periodical
71
Issue of the periodical within the volume
2
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
10
Pages from-to
197-206
UT code for WoS article
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EID of the result in the Scopus database
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