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Liquid-Liquid Equilibrium in Binary System [bmim][PF6] + 1-Butanol

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F06%3A00055034" target="_blank" >RIV/67985858:_____/06:00055034 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Liquid-Liquid Equilibrium in Binary System [bmim][PF6] + 1-Butanol

  • Original language description

    The present paper addresses a study of liquid-liquid equilibrium in binary system 1-butyl-3-methylimidazolium hexafluorophosphate (abbr. [bmim][PF6]) + 1-butanol. Experimental liquid phase behaviour was investigated using a volumetric method and a cloud-point method, the former enabling us to obtain tie lines (compositions of equilibrium phases), the latter providing points of the solubility curve. The acquired results were correlated by the NRTL and the Flory-Huggins equations. In addition, as data were obtained in the critical region of the binary system, they were described using the extended scaling-law equation proposed by Ewing et al.

  • Czech name

    Rovnováha kapalina-kapalina v binárním systému [bmim][PF6] + 1-Butanol

  • Czech description

    Tento článek se zabývá studiem rovnováhy kapalina-kapalina v binárním systému 1-butyl-3-methylimidazolium hexafluorofosfát (zkr. [bmim][PF6]) + 1-butanol. Fázová rovnováhy zde byla studována experimentálně pomocí objemové metody, která nám umožnila získat konody (složení rovnovážných fází), a zákalové metody, pomocí níž byly naměřeny body binodální křivky. Obdržené výsledky byly korelovány modelem NRTL a Floryho-Hugginsovou rovnicí. Navíc, vzhledem k tomu, že byla získána data i v kritické oblasti binárního systému, byla data korelována také neklasickým modelem podle Ewinga a kol.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA104%2F03%2F1555" target="_blank" >GA104/03/1555: State behaviour and phase equilibria in fluid systems</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2006

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Chemical and Engineering Data

  • ISSN

    0021-9568

  • e-ISSN

  • Volume of the periodical

    51

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

    2126-2131

  • UT code for WoS article

  • EID of the result in the Scopus database