Gas-Phase Formation of SiSe in IR Laser-Co-Decomposition of Dimethyl Selenide and 1,3-Disilacyclobutane
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F07%3A00091347" target="_blank" >RIV/67985858:_____/07:00091347 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Gas-Phase Formation of SiSe in IR Laser-Co-Decomposition of Dimethyl Selenide and 1,3-Disilacyclobutane
Original language description
A LIF excitation spectrum of SiSe obtained upon IR laser irradiation of gaseous mixture of 1,3-disilacyclobutane and dimethyl selenide reveals that the previously reported infrared multiple photon co-decomposition of both compounds involves formation ofSiSe. The SiSe formation is explained in terms of dehydrogenation of H2SiSe and elimination of RSeH from RHSiSe2 species (R=CH3, H).
Czech name
Tvorba SiSe při IČ laserově iniciovaném ko-rozkladu dimethyl selenidu a 1,3-disilacyklobutanu v plynné fázi
Czech description
LIF excitační spektrum SiSe získané při IČ laserově iniciovaném ko-rozkladu dimethyl selenidu a 1,3-disilacyklobutanu v plynné fázi je důkazem, že dříve popsaný ko-rozklad obou sloučenin zahrnuje tvorbu SiSe. Tato reakce je vysvětlena pomocí dehydrogenace H2SiSe a eliminace RSeH z RHSiSe2 (R=CH3,H).
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/ME%20846" target="_blank" >ME 846: Laser induced chemical vapour deposition of nanosized metal sulfides</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>O - Projekt operacniho programu
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
692
Issue of the periodical within the volume
18
Country of publishing house
CH - SWITZERLAND
Number of pages
5
Pages from-to
3841-3845
UT code for WoS article
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EID of the result in the Scopus database
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