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Gas-Phase Formation of SiSe in IR Laser-Co-Decomposition of Dimethyl Selenide and 1,3-Disilacyclobutane

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F07%3A00091347" target="_blank" >RIV/67985858:_____/07:00091347 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Gas-Phase Formation of SiSe in IR Laser-Co-Decomposition of Dimethyl Selenide and 1,3-Disilacyclobutane

  • Original language description

    A LIF excitation spectrum of SiSe obtained upon IR laser irradiation of gaseous mixture of 1,3-disilacyclobutane and dimethyl selenide reveals that the previously reported infrared multiple photon co-decomposition of both compounds involves formation ofSiSe. The SiSe formation is explained in terms of dehydrogenation of H2SiSe and elimination of RSeH from RHSiSe2 species (R=CH3, H).

  • Czech name

    Tvorba SiSe při IČ laserově iniciovaném ko-rozkladu dimethyl selenidu a 1,3-disilacyklobutanu v plynné fázi

  • Czech description

    LIF excitační spektrum SiSe získané při IČ laserově iniciovaném ko-rozkladu dimethyl selenidu a 1,3-disilacyklobutanu v plynné fázi je důkazem, že dříve popsaný ko-rozklad obou sloučenin zahrnuje tvorbu SiSe. Tato reakce je vysvětlena pomocí dehydrogenace H2SiSe a eliminace RSeH z RHSiSe2 (R=CH3,H).

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/ME%20846" target="_blank" >ME 846: Laser induced chemical vapour deposition of nanosized metal sulfides</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)<br>O - Projekt operacniho programu

Others

  • Publication year

    2007

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Organometallic Chemistry

  • ISSN

    0022-328X

  • e-ISSN

  • Volume of the periodical

    692

  • Issue of the periodical within the volume

    18

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    5

  • Pages from-to

    3841-3845

  • UT code for WoS article

  • EID of the result in the Scopus database