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Blended Silicone-ionic Liquid Membranes: Transport Properties of Butan-1-ol Vapor

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F10%3A00341297" target="_blank" >RIV/67985858:_____/10:00341297 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22340/10:00023343

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Blended Silicone-ionic Liquid Membranes: Transport Properties of Butan-1-ol Vapor

  • Original language description

    This paper is focused on modeling of sorption and desorption kinetics as well as on equilibrium butan-1-ol vapor sorption in blended poly(dimethylsiloxane)-benzyl-3-butylimidazolium tetrafluoroborate membranes. Based on the generalized Fick's second law,on time-dependent boundary conditions and on two models of equilibrium sorption, the diffusion coefficients of butan-1-ol were calculated from the experimental data using the finite difference modeling. Although anomalous sorption occurred at higher concentrations of butan-1-ol, the diffusion coefficients calculated from the data on sorption and desorption kinetics were in a good agreement. The increase of the ionic liquid content in poly(dimethylsiloxane) elevated the butan-1-ol equilibrium concentration in the membrane, and, at the same time, decreased the values of butan-1-ol diffusion coefficient.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA104%2F08%2F0600" target="_blank" >GA104/08/0600: Ionic membranes for selective separation of liquid mixtures by pervaporation</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    European Polymer Journal

  • ISSN

    0014-3057

  • e-ISSN

  • Volume of the periodical

    46

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

    000273879900013

  • EID of the result in the Scopus database