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An Enhanced Entangled Polymer Model for Dissipative Particle Dynamics

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F12%3A00376392" target="_blank" >RIV/67985858:_____/12:00376392 - isvavai.cz</a>

  • Alternative codes found

    RIV/44555601:13440/12:43883899

  • Result on the web

    <a href="http://dx.doi.org/10.1063/1.3698476" target="_blank" >http://dx.doi.org/10.1063/1.3698476</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1063/1.3698476" target="_blank" >10.1063/1.3698476</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    An Enhanced Entangled Polymer Model for Dissipative Particle Dynamics

  • Original language description

    We develop an alternative polymer model to capture entanglements within the dissipative particle dynamics (DPD) framework by using simplified bond-bond repulsive interactions to prevent bond crossings. We show that structural and thermodynamic propertiescan be improved by applying a segmental repulsive potential (SRP) that is a function of the distance between the midpoints of the segments, rather than the minimum distance between segments. The alternative approach, termed the modified segmental repulsive potential (mSRP), is shown to produce chain structures and thermodynamic properties that are similar to the softly repulsive, flexible chains of standard DPD. Parameters for the mSRP are determined from topological, structural, and thermodynamic considerations. The effectiveness of the mSRP in capturing entanglements is demonstrated by calculating the diffusion and mechanical properties of an entangled polymer melt.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LH12020" target="_blank" >LH12020: Mesoscopic Modeling of Protein-Surface Interactions</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Chemical Physics

  • ISSN

    0021-9606

  • e-ISSN

  • Volume of the periodical

    136

  • Issue of the periodical within the volume

    13

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

  • UT code for WoS article

    000302596500055

  • EID of the result in the Scopus database