Phase Behaviour, Interactions, and Structural Studies of (Amines+Ionic Liquids) Binary Mixtures

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F12%3A00377005" target="_blank" >RIV/67985858:_____/12:00377005 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1002/cphc.201100952" target="_blank" >http://dx.doi.org/10.1002/cphc.201100952</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/cphc.201100952" target="_blank" >10.1002/cphc.201100952</a>

Result language

angličtina

Original language name

Phase Behaviour, Interactions, and Structural Studies of (Amines+Ionic Liquids) Binary Mixtures

Original language description

We present a study on the phase equilibrium behaviour of binary mixtures containing two 1-alkyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide-based ionic liquids, [Cnmim][NTf2] (n = 2 and 4), mixed with diethylamine or triethylamine as a function of temperature and composition using different experimental techniques. Their phase behaviours have been then correlated and predicted by using Flory-Huggins equations and UNIQUAC method. The potential of the COSMO-RS methodology to predict the phaseequilibria was also tested for the studied binary systems. The liquid state structure of the binary mixture [C2mim][NTf2] + diethylamine has also been investigated by molecular dynamics simulation and neutron diffraction. Finally, the absorption of gaseous ethane by the ([C2mim][NTf2] + diethylamine) binary mixture was determined and compared with those observed in the pure solvents.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

ChemPhysChem

ISSN

1439-4235

e-ISSN

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Volume of the periodical

13

Issue of the periodical within the volume

7

Country of publishing house

DE - GERMANY

Number of pages

11

Pages from-to

1825-1835

UT code for WoS article

000303921600024

EID of the result in the Scopus database

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