Thermophysical Properties of Ammonium-Based Bis{(trifluoromethyl)sulfonyl}imide Ionic Liquids: Volumetric and Transport Properties

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F12%3A00380127" target="_blank" >RIV/67985858:_____/12:00380127 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/je300108z" target="_blank" >http://dx.doi.org/10.1021/je300108z</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/je300108z" target="_blank" >10.1021/je300108z</a>

Result language
angličtina
Original language name
Thermophysical Properties of Ammonium-Based Bis{(trifluoromethyl)sulfonyl}imide Ionic Liquids: Volumetric and Transport Properties
Original language description
Density, rheological properties and conductivity of a homologous series of ammonium-based ionic liquids N-alkyl-triethylammonium bis{(trifluoromethyl)sulfonyl}imide were studied at atmospheric pressure as function of alkyl chain length on the cation, aswell as of the temperature from (293.15 to 363.15) K. Furthermore, rheological properties were measured for both pure and water-saturated ionic liquids. An analysis of involved transport properties leads us to a classification of the studied ionic liquids in terms of their ionicity using the Walden plot, from which it is evident that they can be classified as poor ionic liquids. Finally, from measured density data, different volumetric properties i.e. molar volumes and thermal expansion coefficients were determined as function of temperature and of cationic structure.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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